Q. Which of the following electrolytes will have the highest molar conductance at infinite dilution?

निम्नलिखित में से किस इलेक्ट्रोलाइट्स में अनंत तनुकरण पर उच्चतम मोलर चालकता होगी?

A
NaCl
B
MgCl₂
C
AlCl₃
D
Na₂SO₄

Explanation

Molar conductance at infinite dilution depends on number of ions and mobility.
Na₂SO₄ → 2Na⁺ + SO₄²⁻ ⇒ 3 ions

  • Higher number of ions → greater conductance.

Others:

  • NaCl → 2 ions

  • MgCl₂ → 3 ions (but Mg²⁺ is less mobile)

  • AlCl₃ → 4 ions (but Al³⁺ is very small and highly solvated, moves slowly)

Hence, Na₂SO₄ has best balance of ion count and mobility.

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